So even though your voice starts out as one frequency, it ends up as a mix of multiple ones.
This is where helium comes into play. Helium is lighter than air, which means sound moves faster through helium than through air. Nearly three times faster, in fact. So the sound waves bounce around faster in your vocal tract, which amplifies the higher frequencies in your voice.
Instead of helium, if somebody sucks in sulphur hexafluoride which is six times heavier than air, the sound waves would move slower through it amplifying the lower frequencies in your voice.

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